Modern portable electrical devices typically use batteries based on lithium-ion or its evolved technology lithium-ion polymer. Older devices used nickel-cadmium- or nickel metal hydride-based batteries. The similarities in advised use between these technologies are not only distinct, but almost complementary, in the meaning that the ideal use of one is (close to) the worst case use of the other. After looking into the history and the resulting myth, advice of proper use of lithium-ion will be presented, and finally we will conclude by looking into the future. Our main focus is on lithium-ion-based batteries in modern laptops.
History and basics
In 1983 the first commercial portable computer running on batteries became available. It used a battery technology based on nickel-cadmium (NiCd). In the next decade batteries based on nickel metal hydride (NiMH) and lithium-ion (LiON) became publicly available. For some time they fought nose-to-nose for customer's acceptance, ultimately leading to the victory of the LiON-based technology. As a result, most portable computers and digital cameras use LiON-based batteries, while mobile phones are typically based on a battery technology evolved from the LiON-technology called lithium-ion polymer (Li-poly), which are more robust to physical damage and cheaper to produce.
The advantages of the LiON-based batteries is its superb energy to weight ratio relative to its competitors, its slow in-use degeneration rate and the lack of a so-called "memory effect", which is both present in NiCd- and NiMH-based batteries. However, there is a great drawback. Batteries based on LiON-technology are ageing from the moment they are manufactured, regardless of whether they are charged or not. This means that an older, but unused battery will last shorter than a identical battery manufactured more recently. However, this disadvantage does not seems to frighten as much as its advantages attract, resulting in a wide use of LiON technology in many portable electrical devices.
In use, a lithium-ion typically lasts between two and three years or 300 to 500 full discharges/charges. The discharge/charge rate presented here is not depended on complete discharge/charge cycles, that is, if half of the battery's capacity is used twice, the sum of these uses counts as one, not two, full discharge/charge. It should be stated that these numbers are not based on the ageing or degenerating previously commented alone, but also on the average use of these batteries. With optimal use one can expect much better result because the degeneration can be somewhat delayed, but more importantly, the degeneration can be, and in most cases are, greatly accelerated.
Myth and the effect of its use
Since a flawed use of NiCd- or NiMH-based batteries often resulted in a distinct lack of power, these batteries' need for full discharge/charge cycles have become publicly known. That is, these batteries ideal use were to fully discharge the batteries before recharging, and during recharging neither use or cancellation were recommended. These batteries were said to remember early charges or discharges, a memory which resulted in lack of power. This effect was and is widely referred to as the batteries "memory effect", and indeed, such improper use of these batteries will result in high degeneration rate.
LiON-based batteries do not provide such a memory effect. Nevertheless, most people still believe this effect is present in all or most batteries still in use, indeed including the batteries used in devices such as laptops. Not only is this a wrong understanding, but the use of this "knowledge", or should we say myth, is also the main contribution resulting in the accelerated degeneration. That is, fully discharging and recharging LiON-based batteries can and often will have crucial effect on the batteries duration.
If close to fully or fully discharged, a LiON-based battery's internal safety circuit opens and it becomes unusable in the sense that it will not recharge. If it is not fully discharged, there exists some boost functions that can be able to reactivate the protection circuit and make the battery recharge. Standard chargers will not perform such a boost. Furthermore, if the battery is fully discharged and has been in such a state form months, a boost function will probably not only fail, but may also be dangerous. In addition, a LiON-based battery is expected to degenerate faster when close to fully discharged than if kept at a somewhat higher charge level rate.
On the other hand, fully charging the battery is also not recommendable. Thought it is not the charging itself that is the problem, the result of keeping a battery fully charged is crucial. As noted, any LiON-based battery degenerates from the day it was manufactured, however, a fully charged battery degenerates much faster, especially in combination with a warm environment. In a environment of 60 degrees Celsius a fully charged battery will within three months typically degenerate to 60 % of its capacity, while a 40 % charged battery in the same environment will only degenerate to 75 % after a year. From these numbers it should be clear keeping LiON-based batteries fully charged will greatly accelerate its degeneration, and indeed, most users who try to follow the old battery-friendly tip of full discharge/charge cycles keep the charger connected after the battery is fully charged, thus resulting in accelerated degeneration.
Proper use
As noted, LiON-based batteries degenerate much faster when kept close to fully or fully charged. In special situation when extra battery life is needed, like on long trips and so on, one must by all means fully charge the battery. Thought, in such situations the battery should be charged only shortly prior to departure in order to keep the battery fully charged as short as possible. However, in normal situations when one simply sits by the outlet, an easy, but not optimal, solution is to disconnect the charger before the charge level reaches 80 % of full capacity. This should also be done prior to journeys where full battery life is not needed.
To avoid the opening of safety circuits and acceleration of degeneration, it is also recommendable to reconnect the charger when charge level is approximately 20 %. Again, if an outlet is not available and the laptop is needed for use, one must of course keep using the laptop. However, it should be a good reason for forcing the last 5 % out of the battery, since both the danger for opening safety circuits and the level of degeneration increase dramatically while approaching a fully discharged state.
The heuristic of disconnecting and reconnecting the charger is often easy to apply, but does not offer the best result. In the case when one is sitting nearby the outlet, which normally is the typical case, the best solution is to disconnect the battery itself. The battery should be disconnected when the charge level is approximately 40 % and stored properly (see "Storing of lithium-ion batteries"). Please note that disconnecting the battery, thought good for the battery itself, increase the risk of loosing your work to what is present for desktop computers. That is, if one has disconnected the battery and the power fails, the laptop will immediately power off, not leaving any "Do you wish to save the changes" or alike. However, thought varying between each location, normally the power is quite stable, so this downside may not be preponderant.
Storing
As is the case in the recommended use of these batteries, nor in storing is it wise to keep the battery at high or low charge level. The recommended storage charge level is 40 %. The reason this charge level is somewhat high is to keep the battery's protection circuit operational during prolonged storage. Thus, if you plan to store the battery for a shorter period, it might be wise to keep it at a lower charge level, say 20 to 30 %.
The storage environment's temperature can be vital for the battery. Thought freezing the battery is not a good idea, the battery should be kept coldly, about 0 degrees Celsius is a generally good rule of thumb.
To see the effect of these rules of thumb, we previously commented the decreased degenerating achieved by storing a battery at a lower charge level, that is, a fully charged battery stored in a 60 degrees Celsius environment will typically degenerate to 60 % within three months, while a battery stored at 40 % charge level will typically only degenerate to 75 % within a year. Furthermore, if the environment had been of 0 degrees Celsius, one could expect the battery to only degenerate to 98 % in a year, which under the circumstances must be stated as an acceptable degeneration rate. Finally it should be noted that the longer one plans to store the battery, the more important it is to keep these guidelines.
Digital memory
As commented, LiON-based batteries does not possess the "memory effect" present in both NiCd- and NiMH-based batteries. Nonetheless, there is a effect present in these batteries referred to as "digital memory", referring to the memory of a fuel estimate present in many devices using batteries, including both laptops and mobile phones. Short discharges and recharges does not provide synchronization of the fuel estimate and battery's state-of-charge. The effect of this "digital memory" is not related physically to the battery, as was the case for the "memory effect", but it will make the fuel estimate increasingly less accurate. To avoid this effect one performs a calibration by fully discharged and then recharge the battery. To eliminate the failure caused by the "digital memory", it is often recommended to perform a calibration once every 30 charge.
Does lithium-ion-based batteries belong to the future?
Since it became commonly available, the use of LiON-based batteries have been discussed, and still is, thought its competitor based on NiMH is not much used. The technology behind the LiON-based batteries have been continuously developed, and the development is still in progress. By obvious reasons it is of particularly interest to decrease the natural ageing of the LiON-based batteries, and progress has been achieved.
Thought development and progress, it should not come as a total surprise if a new technology claim the battery-throne in the near future. After all, the progress of existing technology typically only results in modest improvements, while users and scientists keep dreaming of laptops lasting weeks – or maybe years. Having said that, progress has been unexpectedly slow in the field of new battery technologies for the consumers marked, so it might remain with the dreams for yet some years to come.
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History of laptops
Is lithium-ion the ideal battery?
Lithium-ion polymer battery
All about laptop batteries
How to prolong lithium-based batteries
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